During Avengers,
Dr. Selvig constructs a device that uses the Tesseract to create a portal. He built in a fail safe, which Black Widow uses to close the portal; he refers to it as, "you can't protect against yourself."
Here, 'yourself' refers to the Tesseract and Loki's staff, as they have matching energy signatures.
However, in Captain America: The Winter Soldier,
Baron Strucker says of Loki's scepter, "[it] is worth more than any of them ever knew," which to me implies that the scepter wasn't just tapping the Tesseract's power (like the Phase 2 weapons would have).
This makes me think the gem in the scepter could be another Infinity Stone. This would make a certain amount of sense, given the similar energy signatures, and that Loki received it from Thanos.
Is the gem in Loki's scepter an Infinity Stone? If so, do we know (or have an educated guess) which one?
Answer
It hasn't been revealed in MCU that gem in Loki's scepter is an Infinity Stone.
But, if it really is an Infinity Stone, my educated guess says that it'd be analogous to the Mind Gem or Soul Gem as Loki used it to control mind or free will of many.
Update:
Avengers: Age of Ultron movie confirms that
The gem in Loki's staff contains an Infinity Stone. It is the Mind Stone.
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